Polymerization of substituted acetylenes by group 5 and 6 transition metal catalysts.
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چکیده
منابع مشابه
Dissymmetric dinuclear transition metal complexes as dual site catalysts for the polymerization of ethylene
A series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization, by coupling the allylated a-diimine complexes of the metals Ti, Zr, V, Ni and Pd with the ansa-zirconocene complex [C5H4-SiH(Me)-C5H4]ZrCl2 possessing a hydride silane moiety. The different stages of syntheses included the formation of bis(cyclopentadienide)methyl silane which was u...
متن کاملGroup 3 metal catalysts for ethylene and -olefin polymerization
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متن کاملdissymmetric dinuclear transition metal complexes as dual site catalysts for the polymerization of ethylene
a series of dissymmetric dinuclear complexes were synthesized, as dual site catalysts in ethylene polymerization,by coupling the allylated a-diimine complexes of the metals ti, zr, v, ni and pd with the ansa-zirconocenecomplex [c5h4-sih(me)-c5h4]zrcl2 possessing a hydride silane moiety. the different stages of syntheses includedthe formation of bis(cyclopentadienide)methyl silane which was util...
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Polyolefins are of vast economic importance, which is reflected by an annual production of more than 70 million tons of polyethylene and polypropylene. While the major portion of these materials is produced with Zieglerand chromium-based catalysts, the older free-radical process that affords low-density polyethylene (LDPE) has maintained its significance.[1] Despite the necessity of working at ...
متن کاملHeteroatom-assisted olefin polymerization by rare-earth metal catalysts
Heteroatom-functionalized polyolefins are of fundamental interest and practical importance. This has spurred investigations of the copolymerization of polar and nonpolar olefins. We report the first syndiospecific polymerization of a series of heteroatom-containing α-olefins and their copolymerization with ethylene catalyzed by half-sandwich rare-earth complexes. We have found that the interact...
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ژورنال
عنوان ژورنال: Journal of Synthetic Organic Chemistry, Japan
سال: 1985
ISSN: 0037-9980,1883-6526
DOI: 10.5059/yukigoseikyokaishi.43.744